Product ID:1,1,1-TRICHLOROETHANE, 9437
MSDS Date:06/09/1994
FSC:6810
NIIN:00N049508
MSDS Number: CBCFS

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865
US

Emergency Phone: 800-424-8802;800-424-9300(CHEMTREC)

Info Phone: 908-859-2151

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 90-100%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM;450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL,RAT) 4200 MG/KG.

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: <3%

OSHA PEL 100 PPM, S

ACGIH TLV: 25 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BUTANE, 1,2-EPOXY-; (1,2-BUTYLENE OXIDE) (SARA 313)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: <0.5%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G.,
EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING
USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
ACUTE: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:P-DIOXANE:IARC MONOGRAPHS, SUPP, VOL 7,
PG 201, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO
BE (SUPP DATA)
Effects of Overexposure:HLTH HAZ:INHAL:MAY CAUSE PULM EDEMA, HDCH,
NAUSEA, VOMITING, DIZZ, DROW, IRRIT OF UPPER RESP TRACT,
UNCONSCIOUSNESS. SKIN CONTACT:IRRIT, PROLONGED CONTACT MAY CAUSE
DERMATITIS. EYE CONTACT:IRRITATION. SKIN ABSORPTION:NONE
IDENTIFIED. INGEST:NAUSEA, VOMITING. CHRONIC:KIDNEY/LIVER DMG.
TARGET ORGANS:CNS, SKIN, EYES, CVS.
Medical Cond Aggravated by Exposure:LIVER DISORDERS, HEART DISORDERS,
SENSITIVE SKIN.

First Aid:INGEST:CALL MD. IF SWALLOWED, DO NOT INDUCE VOMITING.
INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. PROMPT ACTION IS ESSENTIAL.
SKIN:FLUSH W/WATER FOR AT LEAST 15 MINUTES. EYES:IMMEDIATELY FLUSH
W/PLENTY OF WATER FOR AT LEAST 15 MINUTES.

Flash Point Method:CC
Lower Limits:7.5%
Upper Limits:15%
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . NONE IDENTIFIED.

Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
STOP LEAK IF YOU CAN DO SO W/OUT RISK. USE WATER SPRAY TO REDUCE
VAPS. TAKE UP W/SAND OR OTHER NON-COMBUST ABSORB MATL & PLACE INTO
CNTNR FOR LATER DISP. FLUSH SPILL AREA W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. SUITABLE FOR
ANY GEN CHEM STOR AREA. KEEP AWAY FROM FOOD. CAUSES IRRIT. HARMFUL
IF SWALLOWED/INHALED. AVOID BRTHG VAPOR.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE . KEEP OUT OF REACH OF CHILDREN.
WARNING:1,1,1-TR ICHLOROETHANE IS A SUBSTANCE (SUPP DATA)

Respiratory Protection:NONE REQUIRED WHERE ADEQ VENT CNDTNS EXIST. IF
AIRBORNE CONC IS HIGH, A NIOSH/MSHA APPROVED CHEMICAL CARTRIDGE
RESP W/ORGANIC VAPOR CARTRIDGE IS REC. IF CONC EXCEEDS CAPACITY OF
CARTRIDGE RESP, A NIOS H/MSHA APPROVED SCBA IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS. VENT HOOD.
Protective Gloves:POLYVINYL ALCOHOL GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . UNIFORM, APRON ARE RECOMMENDED. LAB COAT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLAN OF CARCIN:CARCIN. ANIMAL:KIDNEY, LIVER. OTHER PREC:WHICH HARMS
PUBLIC HLTH & THE ENVIRON BY DESTROYING THE OZONE IN THE UPPER ATM.
AVOID CONT W/EYES, SKIN, CLTHG. USE W/ADEQ VENT. NOTE:WHEN HND LG
LIQ PRODS, SECONDARY PROT CNTNRS MUST BE USED FOR CARRYING.

Boiling Pt:B.P. Text:165F,74C
Melt/Freeze Pt:M.P/F.P Text:-27F,-33C
Vapor Pres:100 @ 20C
Vapor Density:4.6
Spec Gravity:1.32 (H*2O=1)
Evaporation Rate & Reference:12.8 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE (<0.1%)
Appearance and Odor:COLORLESS LIQUID; FAINT ETHER-LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
WATER, STRONG BASES, ALUMINUM, CHEMICALLY ACTIVE METALS, STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:MOISTURE, INSUFFICIENT INHIBITOR, HEAT,
FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE,
CARBON MONOXIDE.

Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U226
(TOXIC WASTE).

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.